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XIE Zhengchuan, GAO Jie, LIU Chengyan, CHENG Yiran, YU Zhonghai, ZHANG Zhongwei, LI Jiahui, MIAO Lei. Solvothermal preparation of silver selenide and its thermoelectric properties[J]. Journal of Guilin University of Electronic Technology, 2022, 42(4): 297-304.
Citation: XIE Zhengchuan, GAO Jie, LIU Chengyan, CHENG Yiran, YU Zhonghai, ZHANG Zhongwei, LI Jiahui, MIAO Lei. Solvothermal preparation of silver selenide and its thermoelectric properties[J]. Journal of Guilin University of Electronic Technology, 2022, 42(4): 297-304.

Solvothermal preparation of silver selenide and its thermoelectric properties

  • To adopt a low energy consumption and short time-consuming method, high-performance silver selenide (Ag2Se) based thermoelectric materials was prepared. The different silver-selenium molar ratios (nAgNO3/nSe) silver selenide powder was synthesized by solvothermal method using ethylenediamine as the solvent, silver nitrate (AgNO3) and elemental selenium (Se) as raw materials. After spark plasma sintering (SPS) process, the block was obtained. X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to conduct phase analysis and microscopic morphology observation of the sample. The thermoelectric performance test system was used to test the pyroelectric performance of the sample. The performance of the sample was verified by simulation calculation and actual output voltage test of thermoelectric power generation device. The results shows that with the increase of nAgNO3/nSe, the diffraction peak of the second phase Ag element in the silver selenide powder increases, which is beneficial to optimize the carrier transport characteristics of the sample. The highest thermoelectric figure of merit (zT) about 0.74 at room temperature is obtained when the nAgNO3/nSe is 2 ∶1. A maximum zT of 1.07 is achieved at 393 K and its average zT value (zTavg) during 303 K~393 K is about 0.82 when the nAgNO3/nSe is 1.9 ∶1. Simulation calculation and actual output voltage test of thermoelectric power generation show that the experimentally prepared silver selenide bulk thermoelectric material is promising to replace N -type Bi2Te3 based thermoelectric material.
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