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蔡幸然, 徐芬, 孙立贤, 郭晓磊, 韦思跃, 张晨晨, 吴怡, 廖鹿敏, 魏胜, 程日光, 管彦洵, 李彬. 一种新型钴铁双金属配合物的合成及其晶体结构[J]. 桂林电子科技大学学报, 2022, 42(2): 148-153.
引用本文: 蔡幸然, 徐芬, 孙立贤, 郭晓磊, 韦思跃, 张晨晨, 吴怡, 廖鹿敏, 魏胜, 程日光, 管彦洵, 李彬. 一种新型钴铁双金属配合物的合成及其晶体结构[J]. 桂林电子科技大学学报, 2022, 42(2): 148-153.
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CAI Xingran, XU Fen, SUN Lixian, GUO Xiaolei, WEI Siyue, ZHANG Chenchen, WU Yi, LIAO lumin, WEI Sheng, CHENG Riguang, GUAN Yanxun, LI Bin. Synthesis and crystal structure of a novel cobalt-iron binary coordination polymer[J]. Journal of Guilin University of Electronic Technology, 2022, 42(2): 148-153.
Citation: CAI Xingran, XU Fen, SUN Lixian, GUO Xiaolei, WEI Siyue, ZHANG Chenchen, WU Yi, LIAO lumin, WEI Sheng, CHENG Riguang, GUAN Yanxun, LI Bin. Synthesis and crystal structure of a novel cobalt-iron binary coordination polymer[J]. Journal of Guilin University of Electronic Technology, 2022, 42(2): 148-153.
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一种新型钴铁双金属配合物的合成及其晶体结构

Synthesis and crystal structure of a novel cobalt-iron binary coordination polymer

    摘要
  • 摘要: 采用水热法合成了一种结构新颖的二维层状钴铁双金属配合物Co(phen)3·Fe(phen)3·2Co(DPC)2·2Fe(DPC)2·2H2O(phen=1, 10-菲啰啉, DPC=2, 6-吡啶二羧酸)。采用单晶X射线衍射对其结构进行了表征, 测试结果表明, 该配合物属于三斜晶系、P1空间群, 其晶胞参数为: Mr =2 782.43, a=13.102 6(9) nm, b=14.298 9(9) nm, c=18.245 5(10) nm, α =105.117(2)°, β=103.177(2)°, γ=100.122(2)°, V=3111.0(3) Å3, Z=1。

     

    Abstract: A novel cobalt-iron binary coordination polymer Co(phen)3·Fe(phen)3·2Co(DPC)2·2Fe(DPC)2·2H2O has been successfully synthesized hydrothermally by using 2, 6-pyridinedicarboxylic acid, phenanthroline, cobalt nitrate and iron nitrate as the raw materials, ethanol and water as solvents. The structure of the coordination polymer is characterized by X-ray single crystal diffraction. According to the analysis of X-ray single crystal diffraction data, the crystal belongs to triclinic system, space group P1 with Mr=2 782.43, a=13.102 6(9) nm, b=14.298 9(9) nm, c=18.245 5(10) nm, α=105.117(2)°, β=103.177(2)°, γ=100.122(2)°, V=3 111.0(3) Å3, Z=1.

     

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