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熊瑶, 颜东亮. 勃姆石涂层改性锌负极及其电化学性能研究J. 桂林电子科技大学学报, 2025, 45(6): 629-635. DOI: 10.16725/j.1673-808X.202347
引用本文: 熊瑶, 颜东亮. 勃姆石涂层改性锌负极及其电化学性能研究J. 桂林电子科技大学学报, 2025, 45(6): 629-635. DOI: 10.16725/j.1673-808X.202347
XIONG Yao, YAN Dongliang. Investigation of electrochemical properties of zinc anode modified by boehmite coatingJ. Journal of Guilin University of Electronic Technology, 2025, 45(6): 629-635. DOI: 10.16725/j.1673-808X.202347
Citation: XIONG Yao, YAN Dongliang. Investigation of electrochemical properties of zinc anode modified by boehmite coatingJ. Journal of Guilin University of Electronic Technology, 2025, 45(6): 629-635. DOI: 10.16725/j.1673-808X.202347

勃姆石涂层改性锌负极及其电化学性能研究

Investigation of electrochemical properties of zinc anode modified by boehmite coating

  • 摘要: 为了改善水系锌离子电池锌负极在循环过程中发生的枝晶和腐蚀等问题,通过水热法制备了一种层状勃姆石(AlOOH)作为锌负极的表面涂层,以实现均匀的锌离子沉积来缓解腐蚀和锌枝晶的形成。采用扫描电镜和X射线衍射仪来表征材料的结构和形貌,通过恒流长循环性能测试和循环伏安法来研究AlOOH@Zn负极的电化学性能。实验结果表明,勃姆石具有独特的介孔结构和亲锌性,作为锌负极的涂层可以有效抑制锌负极在电解液中的腐蚀,并为Zn2+的快速转移提供大量的纳米通道,以实现均匀的锌离子沉积。AlOOH@Zn负极在循环过程中表现出良好的稳定性和循环寿命,在电流密度为0.5 mA·cm−2时,AlOOH@Zn对称电池表现出低于50 mV的稳定极化电压,与锌负极相比,循环寿命提高了4倍;AlOOH@Zn//NaV3O8·1.5H2O全电池在电流密度为1 A·g−1时可提供238.4 mAh·g−1的高比容量。这说明勃姆石涂层是一种很有前景的抑制水系锌离子电池腐蚀及枝晶的策略。

     

    Abstract: In order to improve the challenges of zinc anode such as dendrites and corrosion in aqueous zinc ion batteries, a layered bohmite (AlOOH) was prepared by the hydrothermal method as the surface coating of zinc anode to achieve uniform deposition of zinc ions to alleviate the corrosion and formation of zinc dendrites. The structure and morphology of the material were characterized by a scanning electron microscope and X-ray diffraction. The electrochemical performance of AlOOH@Zn was investigated by a galvanostatic long-cycle performance test and cyclic voltammetry. The experimental results show that boehmite has a unique mesoporous structure and zincophilic properties. As a coating of zinc anode, it can effectively inhibit the corrosion of zinc anode in electrolyte and provide abundant nano channels for zinc deposition. The AlOOH@Zn anode shows good stability and cycle life during the cycle process. The AlOOH@Zn symmetric battery shows stable polarization below 50 mV and its cycle life is four times that of the bare Zn at 0.5 mA·cm−2. The AlOOH@Zn//NaV3O8·1.5H2O full battery provides a high specific capacity of 238.4 mAh·g−1 at 1 A·g−1. These results indicate that boehmite coating is a promising strategy to inhibit the corrosion and dendrite of aqueous zinc-ion batteries.

     

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